广义超立方体网络中一类容错路由选择

证明了n-维广义超立方体网络Q(m1,m2,…,mn)中,任意两个节点x和y之间存在长度均不超过H(x,y)+2的m1+m2+…+mn-n条内点不交的路由,其中有H(x,y)条长度不超过H(x,y),此处H(x,y)表示x到y的汉明距离.并在此基础上讨论了广义超立方体网络的容错路由问题.证明了即使无效点很多,但只要存在某个(n-1)-维广义超子立方体中无效节点较少,则该n-维广义超立方体中的任意两个有效节点之间可以找到最优路由或接近最优路由的有效路由.     

基底细胞癌新药Sonidegib的合成工艺优化

以2-氯-5-硝基吡啶为起始原料,经氢化、偶联和酰胺缩合反应合成Sonidegib,总收率71.4%,其结构经¹H NMR和MS（ESI）确证。     

Study of Spectral Character of Alkali Metals Using Microwave Plasma Torch Simultaneous Spectrometer

IntroductionIn the past decades, alkali metals were widely ap-plied in many fields, such as applied catalysis[1,2],surface science[3,4], and molecular biology[5]. Micro-wave plasma torch(MPT), developed and improved byYu and coworkers[6,7], is a novel dev…     

小型微波谐振腔用于蛋白质微波辅助酶解

采用微波谐振腔对细胞色素c以及牛血清白蛋白进行微波辅助酶解, 通过电喷雾三级四极杆质谱对得到的肽段进行分析, 证明该方法可用很低的微波功率将蛋白质彻底酶解为多肽. 通过调整微波条件可以使蛋白质的酶解效率基本达到100％, 细胞色素c和牛血清白蛋白的序列覆盖率分别为45％和26％. 该方法不但可将蛋白酶解时间由传统方法的16 h缩短为20 min, 还将功率由使用微波炉时的数百瓦降至20 W.     

二硝酸根二4′，5′-二氮-9′-(4，5-二(硫乙基)-1，3-二硫杂环戊烯-2-叶立德)-芴合镉的合成、结构及光谱性质

Cd(NO₃)₂·4H₂O与配体4′,5′-二氮-9′-(4，5-二(硫乙基)-1，3-二硫杂环戊烯-2-叶立德)-芴(L)在甲醇和二氯甲烷的混合溶剂中生成配合物Cd(NO₃)₂(L)₂。晶体的空间群是Pbcn(#60)，晶体学参数分别是a=1.578 7(2) nm，b=0.987 96(11) nm，c=2.719 5(3) nm。V=4.241 6(8) nm³，Z=4。2个硝酸根离子各提供1个氧原子，2个配体L各提供2个氮原子，形成了镉的6配位结构。晶体结构显示分子通过平面之间的π-π相互作用沿b轴形成柱状结构，这些柱通过中心原子镉(Ⅱ)的配位连接形成二维层状结构，再通过2个硫乙基上的短距离S…S接触进一步形成了三维结构。对其 ¹H NMR、UV-Vis和荧光光谱进行了研究。     

铁、氮共掺杂二氧化钛粉末的制备及光催化活性

Using TiCl₄ as the titanium source, nanoparticles of TiO₂ doped with nitrogen(N-TiO₂) were synthesized by triethylamine. TiO₂ powder codoped with iron and nitrogen(Fe/N-TiO₂) were prepared by adsorption-deposition of Fe³⁺ on N-TiO₂ and calcining at 400 ℃ for 2 h. From the XPS results for N1s binding energy at 399.6 eV and 396.6 eV, it is proposed that the partial N atoms as substitution atoms replace for O atoms in TiO₂ lattice. The onset of the absorption spectrum of Fe/N-TiO₂ has a 45 nm red-shift compared with that of TiO₂. The results of photocatalytic degradation of methylene blue solution indicate that Fe/N-TiO₂(0.45% Fe³⁺) has a higher activity. Its photocatalytic activity is about 2 times as high as that of pure TiO₂ under UV-light, and 3 times under sunlight. Doping of nitrogen in TiO₂ enhances photoresponse in visible light region and doping of Fe³⁺ reduces the recombination of electrons and holes. Both of the above effects are beneficial for improving the performances of Fe/N-TiO₂ photocatalyst.     

Synthesis and magnetism of rare earth (Nd,Gd,Dy,Ho,Er,Y) pentafluoropropionate binuclear complexes with 2-(4''''-methoxy-phenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide

Six compounds of the general formula [Ln(pfpr)3]2(NITPhOMe).nH2O, where Ln=Nd, Gd, Dy, Ho, Er, Y, pfpr=pentafluoropropionate, NITPhOMe=2-(4'-methoxyphenyl)-4,4,5, 5-tetra-methylimidazoline-1-oxyl-3-oxide, and n=4 (for Nd, Dy, Er); 3 (for Gd); 6 (for Ho); 5 (for Y), have been synthesized. These complexes were characterized by elemental analyses, IR, electronic spectra and molar conductances. The variable temperature (4-300 K) magnetic susceptibility of the complex [Gd(pfpr)3]2(NITPhOMe).3H2O was determined. The observed susceptibility data were fit to those from theoretical magnetic equation by least-squares method. The exchange integral, J, was found to be equal to 2.14 cm-1. This indicates a weak ferromagnetic spin-exchange interaction between the radical and the gadolinium(III) ion.     

自动铺丝平行等距轨迹规划算法实现

针对复合材料自动铺丝技术轨迹规划问题,提出了一种新的基于测地线的平行等距轨迹规划算法.该算法首先将已知的第一条轨迹线在曲面上等弧长离散得到若干数据点,然后在数据点处曲线切矢和曲面法矢的向量积方向上利用测地线的短程性获得下一条铺放轨迹上数据点,并利用B样条曲线拟和数据点生成铺放轨迹,最后使轨迹线铺满模具表面.算法中测地线利用微分方程组数值求解得到,以曲面曲线弧长为自变量,可实现等距线求解的自适应步长调整和较高的精度.经实际算例验证,该算法简单实用,精度能够满足铺丝技术工艺要求.     

数码相机在研究阻尼振动中的应用

介绍一种采用数码相机来研究阻尼振动的特性参数及其运动规律的方法.     

部分植被化复式河道水流的二维解析解

运用涡粘模型理论对部分植被化复式河道的水流水深平均流速和边壁切应力分布进行了求解.通过对水流微元体进行纵向受力分析建立相应的控制微分方程,其中植被对水流的影响归结为拖曳力项.同时将复式渠道划分为3个子区域,通过联立求解各区域微分方程中的定解系数,最终得到均匀流的条件下各区水深平均流速的横向分布的解析解.在获得水深平均流速的横向分布后,可进一步给出对泥沙输移有重要影响的河床切应力的横向分布.通过与试验测得的资料比较,表明给出的解析解能够为工程设计提供足够精度的水力特性的预报.